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Proceedings of the National Academy of Sciences of Belarus. Physics and Mathematics Series

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CALCULATION OF ELECT RON ENERGY BANDS AND OPTICAL PARAMETERS OF TIN SULFIDES

Abstract

The electron energy band structure and optical properties of various phases of tin sulfide were theoretically estimated by computer simulation. All the investigated materials were found to be indirect-gap semiconductors with a band gap ranging from 0.17 to 2.4 eV. The band gap in the range of 1.0–1.5 eV and the absorption coefficient near the fundamental absorption edge of more than 105 cm–1 in the cubic and orthorhombic phases of tin sulfide with a stoichiometric composition of SnS make them promising for solar energy conversion.

About the Authors

V. L. SHAPOSHNIKOV
Belarusian State University of Informatics and Radioelectronics
Belarus


A. V. KRIVOSHEEVA
Belarusian State University of Informatics and Radioelectronics
Belarus


V. E. BORISENKO
Belarusian State University of Informatics and Radioelectronics
Belarus


References

1. Luque, A. Will we exceed 50% efficiency in photovoltaics? / A. Luque // J. Appl. Phys. – 2011. – Vol. 110. – P. 031301.

2. High-efficient low-cost photovoltaics: recent developments / eds.: V. Petrova-Koch, R. Hezel, A. Goetzberger. – Berlin; Heidelberg: Springer-Verlag, 2008. – Vol. 140.

3. Madelung, O. Semiconductors: data handbook / O. Madelung. – Berlin; Heidelberg: Springer, 2004.

4. Avellaneda, D. Polymorphic tin sulfide thin films of zinc blende and orthorhombic structures by chemical deposition / D. Avellaneda, M. T. S. Nair, P. K. Nair // J. Electrochem. Soc. – 2008. – Vol. 155. – P. D517–D525.

5. Gao, Ch. Preparation and properties of zinc blende and orthorhombic SnS films by chemical bath deposition / Ch. Gao, H. Shen, L. Sun // Appl. Surf. Sci. – 2011. – Vol. 257. – P. 6750–6755.

6. Optical properties of thermally evaporated SnS thin films / M. M. El-Nahass [et al.] // Opt. Mater. – 2002. – Vol. 20, N 3. – P. 159–170.7. Morphological and thermal properties of β- SnS2 sprayed thin films using Boubaker polynomials expansion / C. Khèlia [et al.] // J. Alloys Compd. – 2009. – Vol. 477. – P. 461–467.

7. Growth and characterization of tin disulfide (SnS2) thin film deposited by successive ionic layer adsorption and reaction (SILAR) technique / N. G. Deshpande [et al.] // J. Alloys Compd. – 2007. – Vol. 436. – P. 421–426.

8. XRD, XPS and 119Sn NMR study of tin sulfides obtained by using chemical vapor transport methods / M. Cruz [et al.] // J. Solid State Chem. – 2003. – Vol. 175. – P. 359–365.

9. Electronic structure of SnS deduced from photoelectron spectra and band-structure calculations / A. R. H. F. Ettema [et al.] // Phys. Rev. B. – 1992. – Vol. 46. – P. 7363–7373.

10. Kresse, G. Efficient interactive schemes for ab initio total-energy calculations using a plane-wave basis set / G. Kresse, J. Furthmüller // Phys. Rev. B. – 1996. – Vol. 54, N 16. – P. 11169–11186.

11. Perdew, J. P. Generalized gradient approximation made simple / J. P. Perdew, K. Burke, M. Ernzerhof // Phys. Rev. Lett. – 1996. – Vol. 77, N 18. – P. 3865–3868.

12. WIEN2k, An augmented plane wave + local orbitals program for calculating crystal properties / P. Blaha [et al.]. – Karlheinz Schwarz, Techn. Universität Wien, Austria, 2001.

13. Shishkin, M. Implementation and performance of the frequency-dependent GW method within the PAW framework / M. Shishkin, G. Kresse // Phys. Rev. B. – 2006. – Vol. 74, N 3. – P. 035101.

14. Tran, F. Accurate band gaps of semiconductors and insulators with a semilocal exchange- correlation potential / Tran F., P. Blaha // Phys. Rev. Lett. – 2009. – Vol. 102, N 22. – P. 226401.


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ISSN 1561-2430 (Print)
ISSN 2524-2415 (Online)