INFLUENCE OF COMPONENT PROPORTIONS OF MICELLAR SOLUTIONS ON THE SPECTRAL PROPERTIES AND SOLUBILIZATION BY PLURONIC OF A BORONDIFLUORIDE DIPYRROMETHENE DERIVATIVE
Abstract
It has been shown by a spectral method that the efficiency of solubilization of a borondifluoride dipyrromethene derivative by Pluronic F-127 inmixed systems depends on the proportions of mass concentrations of the dye and Pluronic in an initial liquid solution. It has been established that the values of the Pluronic F-127 concentration, at which the micelles solubilizing the dye are efficiently formed, exceed 10 % (mass). The analysis of spectral characteristics of the solution of the “dye – Pluronic” adducts has shown that the dye under study exists in the Pluronic micelles in the highest degree of disaggregation manifesting the spectral characteristics of monomeric form.
About the Authors
T. A. Pavich
B. I. Stepanov Institute of Physics of the National Academy of Sciences of Belarus, Minsk
Belarus
Belarus
S. M. Arabei
Belarusian State Agrarian Technical University, Minsk
Belarus
Belarus
R. T. Kuznetsova
Tomsk State University
Russian Federation
Russian Federation
E. G. Martianova
Tomsk State University
Russian Federation
Russian Federation
Y. V. Aksenova
Tomsk State University
Russian Federation
Russian Federation
G. V. Mayer
Tomsk State University
Russian Federation
Russian Federation
M. B. Berezin
G.A. Krestov Institute of Solution Chemistry of the Russian Academy of Sciences, Ivanovo
Russian Federation
Russian Federation
K. N. Solovyov
B. I. Stepanov Institute of Physics of the National Academy of Sciences of Belarus, Minsk
Belarus
Belarus
References
1. Hamley I. W. The Physics of Block Copolymers. Oxford University Press, 1998.
2. Schmolka I. R. // J. Biomed. Mater. Res. 1972. Vol. 6, no. 6. P. 571–582.
3. Gombotz W. R., Pettit D. K. // Bioconjugate Chem. 1995. Vol. 6, no. 4. P. 332–351.
4. Das R. K., Kasoju N., Bora U. // Nanomedicine: Nanotechnology, Biology and Medicine. 2010. Vol. 6, P. 153–160.
5. Liu L., Yong K.-T., Roy I. et al. // Theranostics. 2012. Vol. 2, no. 7. P. 705–713.
6. Foster В, Cosgrove Т, Hammouda В. // Langmuir. 2009. Vol. 25, no. 12. P. 6760–6766.
7. Demina Т., Grozdova I., Krylova O. et al. // Biochemistry. 2005. Vol. 44, no. 10. P. 4042–4054.
8. Кузнецова Р. Т., Аксенова Ю. В., Солодова Т. А. и др. // Оптика и спектроскопия. 2013. T. 115, № 5. C. 797–806.
9. Аксенова Н. А. Особенности функциональных свойств солюбилизированных плюроником фотоактивных соеди- нений, введенных в полимерные матрицы: автореф. дис …. канд. хим. наук. М., 2010.
Review
Views: 611
Email this article 